Preparation of a Polyaniline-Modified Hybrid Graphene Aerogel-Like Nanocomposite for Efficient Adsorption of Heavy Metal Ions from Aquatic Media.

This paper considers the synthesis of a novel nanocomposite based on reduced graphene oxide and oxidized carbon nanotubes modified with polyaniline and phenol-formaldehyde resin and developed through the carbonization of a pristine aerogel. It was tested as an efficient adsorbent to purify aquatic media from toxic Pb(II). Diagnostic assessment of the samples was carried out through X-ray diffractometry, Raman spectroscopy, thermogravimetry, scanning and transmission electron microscopy, and infrared spectroscopy. The carbonized aerogel was found to preserve the carbon framework structure. The sample porosity was estimated through nitrogen adsorption at 77 K. It was found that the carbonized aerogel predominantly represented a mesoporous material having a specific surface area of 315 m2/g. After carbonization, an increase in smaller micropores occurred. According to the electron images, the highly porous structure of the carbonized composite was preserved. The adsorption capacity of the carbonized material was studied for liquid-phase Pb(II) extraction in static mode. The experiment results showed that the maximum Pb(II) adsorption capacity of the carbonized aerogel was 185 mg/g (at pH 6.0). The results of the desorption studies showed a very low desorption rate (0.3%) at pH 6.5 and a rate of about 40% in a strongly acidic medium.

Porous material based on modified carbon and the effect of pore size distribution on the adsorption of methylene blue dye from an aqueous solution.

Carbon porous materials obtained through KOH activation of a furfural + hydroquinone + urotropine mixture were applied as adsorbent for the remediation of methylene blue (MB). The impact of porous structure with special attention to pore size distribution along with well-known pore volume and specific surface area on the remediation of MB was well investigated and elucidated. Findings obtained revealed that pore size distribution plays a crucial role in the liquid-phase adsorption of organic dyes like MB. By varying the synthesis mode parameters, in particular, the activating agent/precursor mass ratio, with the composition and initial components ratios remaining unchanged, samples with different pore size distribution were obtained. It was found that the material predominantly containing pores with an average equivalent diameter of ~ 3.5 nm appears to be the efficient MB adsorbent. The resulting highly porous carbon materials demonstrated high MB adsorption capacity (up to 2555 mg/g). Furthermore, to fully elucidate the adsorption mechanisms occurring on the obtained materials, a comprehensive mathematical processing of experimental data was performed out using the known kinetic and diffusion models (pseudo-first- and pseudo-second order, and intraparticle diffusion), as well as adsorption equilibrium isotherm models (Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich).It can be concluded that the porous carbon materials obtained and described in the present work are effective adsorbents for the removal of MB and may possess great potential for the treatment of dye-containing wastewater.

Polyaniline Modified CNTs and Graphene Nanocomposite for Removal of Lead and Zinc Metal Ions: Kinetics, Thermodynamics and Desorption Studies.

A novel polyaniline-modified CNT and graphene-based nanocomposite (2.32-7.34 nm) was prepared and characterized by spectroscopic methods. The specific surface area was 176 m2/g with 0.232 cm3/g as the specific pore volume. The nanocomposite was used to remove zinc and lead metal ions from water; showing a high removal capacity of 346 and 581 mg/g at pH 6.5. The data followed pseudo-second-order, intraparticle diffusion and Elovich models. Besides this, the experimental values obeyed Langmuir and Temkin isotherms. The results confirmed that the removal of lead and zinc ions occurred in a mixed mode, that is, diffusion absorption and ion exchange between the heterogeneous surface of the sorbent containing active adsorption centers and the solution containing metal ions. The enthalpy values were 149.9 and 158.6 J.mol-1K-1 for zinc and lead metal ions. The negative values of free energies were in the range of -4.97 to -26.3 kJ/mol. These values indicated an endothermic spontaneous removal of metal ions from water. The reported method is useful to remove the zinc and lead metal ions in any water body due to the high removal capacity of nanocomposite at natural pH of 6.5. Moreover, a low dose of 0.005 g per 30 mL made this method economical. Furthermore, a low contact time of 15 min made this method applicable to the removal of the reported metal ions from water in a short time. Briefly, the reported method is highly economical, nature-friendly and fast and can be used to remove the reported metal ions from any water resource.

High-Speed and High-Capacity Removal of Methyl Orange and Malachite Green in Water Using Newly Developed Mesoporous Carbon: Kinetic and Isotherm Studies.

A novel mesoporous carbon nanostructured material was prepared and characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, thermogravimetry, and X-ray diffractometry. The material demonstrated high-speed and high-adsorption capacities of 827.5 and 2484.5 mg g-1 for methyl orange (MO) and malachite green (MG) dyes in 10 min. The kinetic data were fitted to pseudo-first- and pseudo-second-order, external and intraparticle diffusion, and Elovich models, whereas the isotherm data were adjusted to the Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, and Langmuir-Freundlich isotherms (Sips). It was found that MO and MG adsorption was limited by chemical interactions and mixed diffusion. Besides, the physical process was elucidated through free energy values (E = 2.56 and 0.049 kJ mol-1 for the MO and MG, respectively). Methyl orange adsorption mostly occurred through ion exchange and electrostatic interactions, and at lower MO concentrations, through chemical interactions and surface complexation as well. Malachite green adsorption took place only on lower-energy sites. Thus, it can be concluded that the adsorbent proposed herein possessed high-speed and high-adsorption capacity. Therefore, it can be considered as promising in removing the reported dye pollutants.

Graphene based adsorbents for remediation of noxious pollutants from wastewater.

The contamination of water resources with noxious pollutants is a serious issue. Many aquatic systems are contaminated with different toxic inorganic and organic species; coming to wastewater from various anthropogenic sources such as industries, agriculture, mining, and domestic households. Keeping in view of this, wastewater treatment appears to the main environmental challenge. Adsorption is one of the most efficient techniques for removing all most all types of pollutants i.e. inorganics and organics. Nowadays, graphene and its composite materials are gaining importance as nano adsorbents. Graphene; a two-dimensional nanomaterial having single-atom graphite layer; has attracted a great interest in many application areas (including wastewater treatment) due to its unique physico-chemical properties. The present paper is focused on the remediation of noxious wastes from wastewater using graphene based materials as adsorbents, and it contains all the details on materials - i.e., from their synthesis to application in the field of wastewater treatment (removal of hazardous contaminants of different chemical nature - heavy and rare-earth metal ions, and organic compounds - from wastewater effluents. The efficiency of the adsorption and desorption of these substances is considered. Certainly, this article will be useful for nano environmentalist to design future experiments for water treatment.

Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: A review.

The problem of water pollution is of a great concern. Adsorption is one of the most efficient techniques for removing noxious heavy metals from the solvent phase. This paper presents a detailed information and review on the adsorption of noxious heavy metal ions from wastewater effluents using various adsorbents - i.e., conventional (activated carbons, zeolites, clays, biosorbents, and industrial by-products) and nanostructured (fullerenes, carbon nanotubes, graphenes). In addition to this, the efficiency of developed materials for adsorption of the heavy metals is discussed in detail along with the comparison of their maximum adsorption capacity in tabular form. A special focus is made on the perspectives of further wider applications of nanostructured adsorbents (especially, carbon nanotubes and graphenes) in wastewater treatment.